Document Series: Monograph Archive (2026 Edition) / Peer Classification: Applied Photophysics & Optics

Fluorescent Minerals Catalog

Activator Ions, Crystal Physics, Shortwave (254nm) vs Longwave (365nm) Responses & Phosphorescence

Mineral Fluorescence Science

Mineral fluorescence occurs when trace chemical impurities called activators (such as Mn2+, Eu2+, UO22+, Cr3+, or S2-) absorb UV photons and re-emit visible light.

Pure, stoichiometric minerals rarely fluoresce; fluorescence requires specific activator ion concentrations (typically 0.1% to 1%). Conversely, presence of elements like iron (Fe2+ / Fe3+) acts as a quencher, absorbing photon energy non-radiatively and extinguishing fluorescence.

1. Shortwave (254nm) vs Longwave (365nm) Activation

Fluorescent mineral collectors rely on two distinct ultraviolet wavelengths:

Shortwave UV (254 nm / UV-C)

Roughly 85% to 90% of all fluorescent mineral species respond exclusively or most brilliantly to shortwave UV light. The high photon energy of 254 nm (4.88 eV) is required to excite crystal field electronic transitions in minerals like Willemite (neon green) and Calcite (vivid red). Shortwave lamps require fused quartz discharge tubes and specialized solar-blind filters (UG5).

Longwave UV (365 nm / UV-A)

Fewer mineral species respond to longwave UV, but those that do often exhibit spectacular brightness. Classic longwave minerals include Sodalite / Yooperlites (blazing fire-orange), Fluorite (royal blue), Wernerite (sunny yellow), and Ruby / Corundum (laser red). Longwave minerals can be found with battery-operated 365nm filtered LED flashlights.

2. Master Fluorescent Mineral Database

Use the search filter below to search by mineral name, chemical formula, activator, or fluorescence color:

Table 5.1: Master Fluorescent Minerals Reference Database
Mineral Name Formula Crystal System Activator Ion Shortwave (254nm) Longwave (365nm) Phosphorescence Notable Localities
Calcite CaCO3 Trigonal Mn2+ (sensitized by Pb2+ or Ce3+) Brilliant vivid red / orange-red Pale pink, yellow, blue, or inert Strong brief red phosphorescence Franklin & Sterling Hill, New Jersey, USA; Terlingua, Texas, USA
Willemite Zn2SiO4 Trigonal Mn2+ Blinding intense neon green Weak yellowish-green to inert Intense long-lasting green phosphorescence (up to several hours in 'troostite') Sterling Hill Mine, Ogdensburg, New Jersey, USA; Tsumeb, Namibia
Fluorite CaF2 Isometric Eu2+ (divalent Europium), Y3+, Sm3+ Weak violet-blue to white Intense electric royal blue / violet-blue Occasional pale blue phosphorescence; exhibits thermoluminescence Weardale, County Durham, England; Hardin County, Illinois, USA
Sodalite (Yooperlite / Hackmanite) Na8Al6Si6O24Cl2 Isometric S2- (disulfide molecular ion center) Bright orange to fiery salmon-orange Blazing molten fire-orange / bright yellow-orange Strong orange-red phosphorescence; tenebrescence in Hackmanite variety (reversible photochromism) Keweenaw Peninsula / Lake Superior, Michigan, USA ('Yooperlites'); Kola Peninsula, Russia
Autunite Ca(UO2)2(PO4)2·10-12H2O Tetragonal (UO2)2+ (Uranyl ion) Intense bright electric yellow-green Intense bright lime-green / chartreuse Weak green phosphorescence; mineral is naturally radioactive Daybreak Mine, Mount Spokane, Washington, USA; Autun, France
Wernerite (Scapolite) (Na,Ca)4[(Al,Si)12O24](Cl,CO3,SO4) Tetragonal (UO2)2+ or polysulfide ions Weak orange-yellow Blinding brilliant sunny mustard-yellow / canary yellow Moderate yellow phosphorescence Grenville Province, Quebec and Ontario, Canada
Scheelite CaWO4 Tetragonal Intrinsic tungstate [WO4]2- groups (modified by MoO4 replacement) Brilliant bright ice-blue (pure) to golden-yellow (molybdenum-rich powellite series) Inert (does not fluoresce under 365 nm) None Pine Creek Mine, Bishop, California, USA; Mittersill, Austria
Hardystonite Ca2ZnSi2O7 Tetragonal Pb2+ Deep royal indigo-blue / violet-blue Inert None Franklin Mine, Franklin, Sussex County, New Jersey, USA (Type Locality)
Esperite PbCa2Zn3(SiO4)4 Monoclinic Mn2+ Brilliant canary yellow to lemon yellow Inert None Franklin Mine, Franklin, Sussex County, New Jersey, USA
Benitoite BaTiSi3O9 Hexagonal Ti4+ intrinsic octahedral complex Vivid sky-blue to bright cobalt blue Inert to very faint dull red None Dallas Gem Mine, San Benito County, California, USA
Hyalite Opal (Uranyl-activated Opal) SiO2·nH2O Amorphous (UO2)2+ (Uranyl trace impurity) Vivid glowing neon green Vivid glowing neon apple-green / chartreuse (fluoresces even in indirect sunlight!) Weak green phosphorescence Zacatecas, Mexico; Valec, Czech Republic; Erongo, Namibia
Aragonite CaCO3 Orthorhombic Mn2+, organic humic acids, or uranyl ions Bright rose-pink, cream, or bright green Warm butter-yellow, white, or salmon-pink Strong long-lasting cream or greenish phosphorescence Girgenti, Sicily, Italy; Tazewell County, Virginia, USA
Sphalerite (Zn,Fe)S Isometric Cu+, Ag+, or Mn2+ (low iron content required) Weak orange to inert Blazing bright fiery golden-orange or bright pink Sensational long-lasting triboluminescence (flashes orange when scratched) and phosphorescence Balmat, St. Lawrence County, New York, USA; Franklin, New Jersey, USA
Tremolite Ca2(Mg5)Si8O22(OH)2 Monoclinic Mn2+ or Cr3+ Bright yellow, creamy white, or orange Pink to pale yellow Moderate yellow phosphorescence Balmat / Gouverneur, St. Lawrence County, New York, USA
Eucryptite LiAlSiO4 Trigonal Ti4+ or Mn2+ Brilliant cherry red / crimson Inert None Bikita Pegmatite, Masvingo, Zimbabwe; Harding Mine, Dixon, New Mexico, USA
Powellite CaMoO4 Tetragonal Intrinsic molybdate [MoO4]2- complex Brilliant creamy golden-yellow Pale cream-yellow to inert None Jalgaon, Maharashtra, India; Tonopah, Nevada, USA
Clinohedrite CaZnSiO4·H2O Monoclinic Mn2+ Intense rich bright orange Inert Weak orange phosphorescence Franklin, Sussex County, New Jersey, USA
Margarosanite Pb(Ca,Mn)2Si3O9 Triclinic Mn2+ / Pb2+ Spectacular sky-blue with ruby-red and orange highlights Weak violet to inert None Franklin, Sussex County, New Jersey, USA; Langban, Sweden
Tugtupite Na4AlBeSi4O12Cl Tetragonal S2- molecular center Intense fiery crimson red Bright salmon-orange to peach-red Spectacular long-lasting crimson phosphorescence; photochromic (deepens to purple-red under sunlight) Ilimaussaq Complex, Narsaq, Kujalleq, Greenland
Corundum (Ruby) Al2O3:Cr Trigonal Cr3+ (trivalent Chromium) Weak dull red Intense fiery laser red (692.8 nm and 694.3 nm R-lines) Brief red phosphorescence Mogok, Mandalay Region, Myanmar; Jegdalek, Afghanistan; Luc Yen, Vietnam